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. 2008 Jul 7;47(13):5567-9.
doi: 10.1021/ic8007798. Epub 2008 Jun 7.

Ionothermal synthesis of homochiral framework with acetate-pillared cobalt-camphorate architecture

Shumei Chen  1 , Jian Zhang, Xianhui Bu
Affiliations

Ionothermal synthesis of homochiral framework with acetate-pillared cobalt-camphorate architecture

Shumei Chen et al. Inorg Chem. .

Abstract

A new organically templated homochiral material (EMIm)[Co 2( d-cam) 2(ac)] ( 1; d-H 2cam = d-camphoric acid; ac = acetate; EMIm = 1-ethyl-3-methylimidazolium) has been ionothermally synthesized, and it features an unusual acetate-pillared cobalt-camphorate architecture encapsulating the cationic component of the ionic liquid.

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Figures

Figure 1
Figure 1
Crystal structure of 1 showing the atom-labeling scheme with 30% probability. Hydrogen atoms were omitted for clarity. [Symmetry code: (a) −1/2+x, 3/2−y, −1−z; (b) −1/2+x, 1/2−y, −1−z; (c) −1/2−x, 1−y, −1/2+z.]
Figure 2
Figure 2
(a) The 6-connected paddle wheel unit in 1; (b) view of the 3D pillared framework of 1 along the a axis, showing channels occupied by the EMIm cations.
Figure 3
Figure 3
(a) View of the EMIm cation in the 4-membered ring, the outside methyl groups are highlighted by green arrows; (b) view of the 3D pillared framework of 1 along the b axis, showing two types of channels.
See this image and copyright information in PMC

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References

    1. Seo JS, Whang D, Lee H, Jun SI, Oh J, Jeon YJ, Kim K. Nature. 2000;404:982. - PubMed
    2. Vaidhyanathan R, Bradshaw D, Rebilly J-N, Barrio JP, Gould JA, Berry NG, Rosseinsky MJ. Angew. Chem. Int. Ed. 2006;45:6495. - PubMed
    3. Kepert CJ, Prior TJ, Rosseinsky MJ. J. Am. Chem. Soc. 2000;122:5158.
    4. Bradshaw D, Prior TJ, Cussen EJ, Claridge JB, Rosseinsky MJ. J. Am. Chem. Soc. 2004;126:6106. - PubMed
    1. Kesanli B, Lin W. Coord. Chem. Rev. 2003;246:305.
    2. Wu C-D, Lin W. Chem. Commun. 2006:3673. - PubMed
    3. Wu CD, Lin W. Angew. Chem. Int. Ed. 2005;44:1958. - PubMed
    1. Guillou N, Livage C, Drillon M, Férey G. Angew. Chem. Int. Ed. 2003;42:5314. - PubMed
    2. Dybtsev DN, Yutkin MP, Peresypkina EV, Virovets AV, Serre C, Férey G, Fedin VP. Inorg. Chem. 2007;46:6843. - PubMed
    1. Zhang J, Bu X. Angew. Chem. Int. Ed. 2007;46:6115. - PubMed
    2. Zhang J, Chen S, Valle H, Wong M, Austria C, Cruz M, Bu X. J. Am. Chem. Soc. 2007;129:14168. - PMC - PubMed
    3. Zhang J, Yao Y-G, Bu X. Chem. Mater. 2007;19:5083.
    4. Zhang J, Bu X. Chem. Commun. 2008:444. - PubMed
    5. Zhang J, Liu R, Feng P, Bu X. Angew. Chem. Int. Ed. 2007;46:8388. - PubMed
    6. Zhang J, Chew E, Chen S, Pham JTH, Bu X. Inorg. Chem. 2008;47:3495. - PubMed
    1. Attfield MP, Al-Ebini Y, Pritchard RG, Andrews EM, Charlesworth RJ, Hung W, Masheder BJ, Royal DS. Chem. Mater. 2007;19:316.
    2. Harvey G, Herve AC, Hailes HC, Attfield MP. Chem. Mater. 2004;16:3756.
    3. Harvey G, Teat SJ, Tang CC, Cranswick LM, Attfield MP. Inorg. Chem. 2003;42:2428. - PubMed

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