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. 2008 Jul 2;130(26):8160-1.
doi: 10.1021/ja802818t. Epub 2008 Jun 10.

Asymmetric [2 + 2] olefin cross photoaddition in a self-assembled host with remote chiral auxiliaries

Yuki Nishioka  1 , Takumi Yamaguchi, Masaki Kawano, Makoto Fujita
Affiliations

Asymmetric [2 + 2] olefin cross photoaddition in a self-assembled host with remote chiral auxiliaries

Yuki Nishioka et al. J Am Chem Soc. .

Abstract

Remote chirality at the periphery of a self-assembled cage brings about the slight twist of aromatic rings, which is yet sufficient to induce considerable asymmetric induction (up to 50% ee) in the hitherto unknown [2 + 2] cross photoadditions of fluoranthenes.

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