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. 2008 Jul;56(7):973-6.
doi: 10.1248/cpb.56.973.

Rh-N-heterocyclic carbene (NHC) complex-catalyzed addition of phenylboronic acid to N-sulfonyl and N-phosphinoyl aldimines

Abu Bakar Md  1 , Yumiko Suzuki, Masayuki Sato
Affiliations
Free article

Rh-N-heterocyclic carbene (NHC) complex-catalyzed addition of phenylboronic acid to N-sulfonyl and N-phosphinoyl aldimines

Abu Bakar Md et al. Chem Pharm Bull (Tokyo). 2008 Jul.
Free article

Abstract

Rh-N-heterocyclic carbene (NHC) complexes were generated in situ from imidazolium salts, [RhCl(cod)](2) and t-BuOK in dioxane. In the presence of a catalytic amount of Rh-NHC complexes, the addition reaction of phenylboronic acid to N-sulfonylarylimines and N-phosphinyolarylimines gave the corresponding amines in high yields.

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