Effect of sintering time on biaxial strength of zirconium dioxide

Abstract

Objectives: Aim of this study was to evaluate effect of sintering time on mechanical properties of yttrium partially stabilized zirconia (Y-TZP) (ICE Zirkon, ZirkonZahn, Italy).

Methods: Fifty-six zirconia discs were divided into two groups. Discs of the first group were sintered in sintering oven (ZirkonZahn) at 20-1500 degrees C temperature using rise time of 3 h and kept at 1500 degrees C for 2 h. Discs of the second group were sintered at 20-1500 degrees C using rise time of 1h 40 min and kept at 1500 degrees C for 1 h. Half of the discs (n=15) from both groups were thermocycled in distilled water for 20000 cycles (5-55 degrees C). Biaxial flexural strength of the discs (diameter 19.0 mm, thickness 1.6 mm) were measured dry at room temperature. Surface microhardness (VHN) was also measured. X-Ray diffraction analysis was performed to evaluate the ratio of tetragonal to monoclinic phase in thermocycled discs. The data was calculated using Weibull and ANOVA analysis.

Results: No statistically significant difference (p>0.05) was found between the groups in terms of sintering time or thermocycling. The biaxial flexural strength of the groups varied from 995MPa to 1127MPa. Surface microhardness varied from 1478 to 1532. The relative amount of the monoclinic phase was higher when zirconia was thermocycled and stored in water compared to control discs, which had no monoclinic phase at all.

Significance: Variation in the sintering time from 1.6h to 3.0 h did not influence mechanical properties of Y-TZP zirconia.