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. 2008;47(32):6011-4.

doi: 10.1002/anie.200801423.

Asymmetric oxidative cation/olefin cyclization of polyenes: evidence for reversible cascade cyclization

Charles A Mullen¹, Alison N Campbell, Michel R Gagné

Affiliations

PMID: 18649296
PMCID: PMC2908993
DOI: 10.1002/anie.200801423

Asymmetric oxidative cation/olefin cyclization of polyenes: evidence for reversible cascade cyclization

Charles A Mullen et al. Angew Chem Int Ed Engl. 2008.

. 2008;47(32):6011-4.

doi: 10.1002/anie.200801423.

Authors

Charles A Mullen¹, Alison N Campbell, Michel R Gagné

Affiliation

¹ Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, NC 27599-3290, USA.

PMID: 18649296
PMCID: PMC2908993
DOI: 10.1002/anie.200801423

No abstract available

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Figures

Figure 1
X-ray crystallographic structure of [(3)PtCl₂]. Bond angles include P-Pt-P (103.75°), average P-Pt-Cl (85.00°), and Cl-Pt-Cl (87.58°).

Scheme 1 — Scheme 1
Proposed catalytic cycle for [P₂Pt²⁺]-catalyzed polycyclization.

Scheme 2 — Scheme 2
Stoichiometric reactivity of the alkyl–nitrile resting state.

Scheme 3 — Scheme 3
Proton-coupled retrocyclization.

See this image and copyright information in PMC

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