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. 2008;47(32):6011-4.
doi: 10.1002/anie.200801423.

Asymmetric oxidative cation/olefin cyclization of polyenes: evidence for reversible cascade cyclization

Charles A Mullen  1 , Alison N Campbell, Michel R Gagné
Affiliations

Asymmetric oxidative cation/olefin cyclization of polyenes: evidence for reversible cascade cyclization

Charles A Mullen et al. Angew Chem Int Ed Engl. 2008.
No abstract available

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Figures

Figure 1
Figure 1
X-ray crystallographic structure of [(3)PtCl2]. Bond angles include P-Pt-P (103.75°), average P-Pt-Cl (85.00°), and Cl-Pt-Cl (87.58°).
Scheme 1
Scheme 1
Proposed catalytic cycle for [P2Pt2+]-catalyzed polycyclization.
Scheme 2
Scheme 2
Stoichiometric reactivity of the alkyl–nitrile resting state.
Scheme 3
Scheme 3
Proton-coupled retrocyclization.
See this image and copyright information in PMC

References

    1. Yoder RA, Johnston JN. Chem. Rev. 2005;105:4730–4756. - PMC - PubMed
    2. Wendt KU, Schulz GE, Corey EJ, Liu DR. Angew. Chem. 2000;112:2930–2952. - PubMed
    3. Angew. Chem. Int. Ed. 2000;39:2812–2833. - PubMed
    4. Abe I, Rhomer M, Prestwich GD. Chem. Rev. 1993;93:2189–2206.

    1. See reference Nicolaou KC, Edmonds DJ, Bulger PG. Angew. Chem. 2006;118:7292–7344. Angew. Chem. Int. Ed. 2006;45:7134–7186. and also, for example, Kurdyumov AV, Hsung RP. J. Am. Chem. Soc. 2006;128:6272–6273.

    1. Sakakura A, Ishihara K. Chem. Today. 2007;25:9–12.
    1. Ishibashi H, Ishihara K, Yamamoto H. J. Am. Chem. Soc. 2004;126:11122–11123. - PubMed
    2. Kumazawa K, Ishihara K, Yamamoto H. Org. Lett. 2004;6:2551–2554. - PubMed
    3. Grütter C, Alonso E, Chougnet A, Woggon W-D. Angew. Chem. 2006;118:1144–1148. - PubMed
    4. Angew. Chem. Int. Ed. 2006;45:1126–1130. - PubMed
    1. Sakakura A, Ukai A, Ishihara K. Nature. 2007;445:900–903. - PubMed

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