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. 2007 Jul 30;48(31):5461-5464.
doi: 10.1016/j.tetlet.2007.05.179.

Revised structure of deacetyl-1,10-didehydrosalvinorin G

Zhongze Ma  1 , David Y W Lee
Affiliations

Revised structure of deacetyl-1,10-didehydrosalvinorin G

Zhongze Ma et al. Tetrahedron Lett. .

Abstract

In comparison with the NMR data of salvinorin A and its 8-epimer, the published structure of deacetyl-1,10-didehydrosalvinorin G was revised to its 8-epimer. The stereochemistry of 8-epi-deacetyl-1,10-didehydrosalvinorin G was further confirmed by NOESY and chemical synthesis.

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Figures

Figure 1
Figure 1
Conformational structures of 2a and 2b
Figure 2
Figure 2
Key NOE interactions of 2b
Scheme 1
Scheme 1
None
See this image and copyright information in PMC

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