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. 2008 Sep 17;130(37):12248-9.
doi: 10.1021/ja804838y. Epub 2008 Aug 23.

Catalytic enantioselective aldol additions of alpha-isothiocyanato imides to aldehydes

Le Li  1 , Eric G Klauber, Daniel Seidel
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Catalytic enantioselective aldol additions of alpha-isothiocyanato imides to aldehydes

Le Li et al. J Am Chem Soc. .

Abstract

Highly enantioselective organocatalytic aldol additions of alpha-isothiocyanato imides to aldehydes are reported. These reactions provide convenient access to enantiomerically enriched and protected beta-hydroxy-alpha-amino acids with catalyst loadings as low as 1 mol%.

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