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. 2008 Dec 19;73(24):9692-7.
doi: 10.1021/jo801708q.

Total synthesis of citrafungin A

Frederick Calo  1 , Jeffery Richardson, Anthony G M Barrett
Affiliations

Total synthesis of citrafungin A

Frederick Calo et al. J Org Chem. .

Abstract

The antifungal natural product citrafungin A was synthesized using, as key steps, an asymmetric aldol reaction of a chiral oxazolidinone, diastereoselective alkylation of a chiral 1,3-dioxolan-2-one, semihydrogenation of an enyne, and selective methyl ester deprotection.

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