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. 2008 Nov 7:(41):5125-7.
doi: 10.1039/b810574j. Epub 2008 Sep 24.

Adsorption properties and structure of CO2 adsorbed on open coordination sites of metal-organic framework Ni2(dhtp) from gas adsorption, IR spectroscopy and X-ray diffraction

Pascal D C Dietzel  1 , Rune E Johnsen, Helmer Fjellvåg, Silvia Bordiga, Elena Groppo, Sachin Chavan, Richard Blom
Affiliations

Adsorption properties and structure of CO2 adsorbed on open coordination sites of metal-organic framework Ni2(dhtp) from gas adsorption, IR spectroscopy and X-ray diffraction

Pascal D C Dietzel et al. Chem Commun (Camb). .

Abstract

The microporous metal-organic framework Ni(2)(dhtp) (H(4)dhtp=2,5-dihydroxyterephthalic acid) shows distinct end-on CO(2) coordination to coordinatively unsaturated nickel sites giving rise to high CO(2) adsorption capacity at sub-atmospheric pressures and ambient temperatures.

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