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. 1995 Nov;42(11):1625-30.
doi: 10.1016/0039-9140(95)01621-x.

Sorption and preconcentration of metal ions in ethanol solution with a silica gel surface chemically modified with benzimidazole

N L Filho  1 , Y Gushikem, W L Polito, J Moreira, E O Ehirim
Affiliations

Sorption and preconcentration of metal ions in ethanol solution with a silica gel surface chemically modified with benzimidazole

N L Filho et al. Talanta. 1995 Nov.

Abstract

The adsorption isotherms of MCl(2) (M Mn, Ni, Cu, Zn and Cd) and FeCl(3) by silica gel chemically modified with benzimidazole molecules ( Si(CH(2))(3)NC(7)H(5)N) were studied in ethanol solution at 298 K. A column made of modified silica was used to adsorb and preconcentrate the above metal ions from ethanol solution. Elution was done with 0.1 M hydrochloric acid in an ethanol/water mixture having a mole fraction of water of 0.8. The material was applied in the preconcentration of metal ions from commercial ethanol normally used as engine fuel.

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