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. 2008 Dec 24;130(51):17232-3.
doi: 10.1021/ja8069133.

Catalytic enantioselective intermolecular hydroacylation: rhodium-catalyzed combination of beta-S-aldehydes and 1,3-disubstituted allenes

James D Osborne  1 , Helen E Randell-Sly, Gordon S Currie, Andrew R Cowley, Michael C Willis
Affiliations

Catalytic enantioselective intermolecular hydroacylation: rhodium-catalyzed combination of beta-S-aldehydes and 1,3-disubstituted allenes

James D Osborne et al. J Am Chem Soc. .

Abstract

A rhodium(I) catalyst incorporating the Me-DuPhos ligand promotes enantioselective intermolecular hydroacylation between beta-S-aldehydes and 1,3-disubstituted allenes. The nonconjugated enone products are obtained in good yields and with high enantioselectivities.

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