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. 2009;48(10):1766-70.
doi: 10.1002/anie.200804836.

Heterogeneously hybridized porous coordination polymer crystals: fabrication of heterometallic core-shell single crystals with an in-plane rotational epitaxial relationship

Shuhei Furukawa  1 , Kenji Hirai, Keiji Nakagawa, Yohei Takashima, Ryotaro Matsuda, Takaaki Tsuruoka, Mio Kondo, Rie Haruki, Daisuke Tanaka, Hirotoshi Sakamoto, Satoru Shimomura, Osami Sakata, Susumu Kitagawa
Affiliations

Heterogeneously hybridized porous coordination polymer crystals: fabrication of heterometallic core-shell single crystals with an in-plane rotational epitaxial relationship

Shuhei Furukawa et al. Angew Chem Int Ed Engl. 2009.

Abstract

MOF on MOF: Core-shell porous coordination polymer (PCP) crystals are fabricated at the single-crystal level by epitaxial growth in solution. Synchrotron X-ray diffraction measurements unveiled the structural relationship between the shell crystal and the core crystal, where in-plane rotational epitaxial growth compensates the difference in lattice constant.

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