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. 2009;48(7):1321-3.
doi: 10.1002/anie.200805392.

Gas-phase versus liquid-phase structures by electrospray ionization mass spectrometry

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Gas-phase versus liquid-phase structures by electrospray ionization mass spectrometry

Zhixin Tian et al. Angew Chem Int Ed Engl. 2009.

Abstract

Preferred protonation: Does electrospray ionization mass spectrometry produce gas-phase or liquid-phase structures? The preferred protonation site in p-aminobenzoic acid depends upon the medium, and the structure of its conjugate acid varies with the solvent used during spraying.

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