Gas-phase versus liquid-phase structures by electrospray ionization mass spectrometry
- PMID: 19130534
- DOI: 10.1002/anie.200805392
Gas-phase versus liquid-phase structures by electrospray ionization mass spectrometry
Abstract
Preferred protonation: Does electrospray ionization mass spectrometry produce gas-phase or liquid-phase structures? The preferred protonation site in p-aminobenzoic acid depends upon the medium, and the structure of its conjugate acid varies with the solvent used during spraying.
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