doi: 10.1002/anie.200805321.
Formation of patches on 3D SAMs driven by thiols with immiscible chains observed by ESR spectroscopy
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- PMID: 19180612
- DOI: 10.1002/anie.200805321
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Formation of patches on 3D SAMs driven by thiols with immiscible chains observed by ESR spectroscopy
Angew Chem Int Ed Engl.
2009.
Abstract
Beyond stripes: The extreme lipophobicity of perfluorinated chains attached to amphiphilic thiolates triggers the formation of "stars" (or patches) surrounded by amphiphilic alkylthiolates in three-dimensional self-assembled monolayers. This strategy led to the first example of a water-soluble multicompartment monolayer wrapped around a gold core.
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