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. 2009 Feb 11;131(5):1668-9.
doi: 10.1021/ja808940n.

Metal-free oxidative cross-coupling of unfunctionalized aromatic compounds

Yasuyuki Kita  1 , Koji Morimoto, Motoki Ito, Chieko Ogawa, Akihiro Goto, Toshifumi Dohi
Affiliations

Metal-free oxidative cross-coupling of unfunctionalized aromatic compounds

Yasuyuki Kita et al. J Am Chem Soc. .

Abstract

A new strategy for mixed biaryl synthesis has been developed using the hypervalent iodine(III) reagents. The unique reactivities of the sigma-heteroaryl iodine(III) intermediates generated in situ are the key element for the unusual metal catalyst-free transformations and strict control of the product selectivities.

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