The double solubility rule holds for racemizing enantiomers
- PMID: 19222072
- DOI: 10.1002/chem.200801847
The double solubility rule holds for racemizing enantiomers
Abstract
Chiral amnesia: Experimental results demonstrate that the double solubility rule indeed holds true for the solution-phase enantiomers of a conglomerate-forming solid under fast-racemizing conditions. There is neither experimental evidence for chiral recognition via solution-phase clusters nor a need to invoke them to produce a lucid explanation of the compelling model for the evolution of solid-phase homochirality first communicated by Viedma.
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