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. 2009 Mar 21:(11):1398-400.
doi: 10.1039/b820674k. Epub 2009 Jan 21.

Bridgehead enolates and bridgehead alkenes in a welwistatin model series

Valerie Boissel  1 , Nigel S Simpkins, Gurdip Bhalay, Alexander J Blake, William Lewis
Affiliations

Bridgehead enolates and bridgehead alkenes in a welwistatin model series

Valerie Boissel et al. Chem Commun (Camb). .

Abstract

Bridgehead metallation is possible in a ketone having the welwistatin skeleton, and this facilitates installation of the isothiocyanate function present in the natural product, and also enables synthesis of remarkable bridgehead alkenes.

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