Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2009 Apr 8;131(13):4600-1.
doi: 10.1021/ja900880z.

Oxidative addition of ammonia at a silicon(II) center and an unprecedented hydrogenation reaction of compounds with low-valent group 14 elements using ammonia borane

Anukul Jana  1 , Carola Schulzke, Herbert W Roesky
Affiliations

Oxidative addition of ammonia at a silicon(II) center and an unprecedented hydrogenation reaction of compounds with low-valent group 14 elements using ammonia borane

Anukul Jana et al. J Am Chem Soc. .

Abstract

The reaction of L'Si [L' = CH{(C=CH(2))(CMe)(2,6-iPr(2)C(6)H(3)N)(2)}] with ammonia under oxidative addition results in L'Si(H)NH(2). H(3)NBH(3) functions as a source of hydrogen for the hydrogenation of N-heterocyclic carbenes and germylenes.

PubMed Disclaimer

LinkOut - more resources