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. 2009 Apr 14:(14):1843-5.
doi: 10.1039/b821398d. Epub 2009 Feb 19.

Pentavalent uranyl stabilized by a dianionic bulky tetradentate ligand

Pawel Horeglad  1 , Grégory Nocton, Yaroslav Filinchuk, Jacques Pécaut, Marinella Mazzanti
Affiliations

Pentavalent uranyl stabilized by a dianionic bulky tetradentate ligand

Pawel Horeglad et al. Chem Commun (Camb). .

Abstract

A pentavalent uranyl complex supported by a bulky dianionic tetradentate (ONNO)-type salan ligand has been prepared by direct synthesis from the iodide precursor {[UO(2)Py(5)][KI(2)Py(2)]}(n), and displays high stability towards disproportionation and ligand dissociation but reactivity towards oxidizing substrates.

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