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. 2009 Apr 14:(14):1909-11.
doi: 10.1039/b823249k. Epub 2009 Feb 23.

Aromatic trifluoromethylation catalytic in copper

Masahiro Oishi  1 , Hideaki Kondo, Hideki Amii
Affiliations

Aromatic trifluoromethylation catalytic in copper

Masahiro Oishi et al. Chem Commun (Camb). .

Abstract

Cu(I)-diamine complexes were found to catalyse the trifluoromethylation of aryl iodides. In the presence of a small amount of CuX (X = Cl, Br, I) and 1,10-phenanthroline (phen), the cross-coupling reactions of iodoarenes with trifluoromethylsilanes proceeded smoothly to afford trifluoromethylated aromatics in good yields.

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