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. 2009 May 13;131(18):6368-9.
doi: 10.1021/ja901731z.

Interconversion between molecular polyhedra and metal-organic frameworks

Jian-Rong Li  1 , Daren J Timmons, Hong-Cai Zhou
Affiliations

Interconversion between molecular polyhedra and metal-organic frameworks

Jian-Rong Li et al. J Am Chem Soc. .

Abstract

The construction of a metal-organic framework (MOF) with a pcu-a topology using a preassembled soluble molecular octahedron has been realized experimentally. The resulting MOF can also be reversibly converted to the molecular octahedron. All such conversions are based on axial-ligand substitution reactions on the molecular octahedron.

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