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. 2009;48(26):4747-50.
doi: 10.1002/anie.200900756.

Metal-ion-coated graphitic nanotubes: controlled self-assembly of a pyridyl-appended gemini-shaped hexabenzocoronene amphiphile

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Metal-ion-coated graphitic nanotubes: controlled self-assembly of a pyridyl-appended gemini-shaped hexabenzocoronene amphiphile

Wei Zhang et al. Angew Chem Int Ed Engl. 2009.

Abstract

The assembly line: Hexabenzocoronene amphiphiles appended with pyridyl-terminated triethylene glycol side chains, in combination with trans-[Pt(PhCN)(2)Cl(2)], lead to the formation of graphitic nanotubes. The structural features and dimensions of the nanotubes depend on the assembly conditions. A platinum(II)-bridged cyclic dimer having two HBC units self-assembles into a nanotubular structure.

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