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. 2009 Jul 7:(25):3762-4.
doi: 10.1039/b905859a. Epub 2009 May 12.

Bis-rhodium hexaphyrins: metalation of [28]hexaphyrin and a smooth Hückel aromatic-antiaromatic interconversion

Harapriya Rath  1 , Naoki Aratani, Jong Min Lim, Jae Seok Lee, Dongho Kim, Hiroshi Shinokubo, Atsuhiro Osuka
Affiliations

Bis-rhodium hexaphyrins: metalation of [28]hexaphyrin and a smooth Hückel aromatic-antiaromatic interconversion

Harapriya Rath et al. Chem Commun (Camb). .

Abstract

Metalation of [28]hexaphyrin(1.1.1.1.1.1) with [RhCl(CO)(2)](2) resulted in the formation of an antiaromatic bis-Rh(i) complex, which can be oxidized to an aromatic bis-Rh(i) complex with retention of its rectangular structure.

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