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. 2009 Aug 7:(29):4408-10.
doi: 10.1039/b907042g. Epub 2009 Jun 10.

Use of 4-piperidones in one-pot syntheses of novel, high-molecular-weight linear and virtually 100%-hyperbranched polymers

Alfredo R Cruz  1 , Mikhail G Zolotukhin, Salvador L Morales, Jorge Cardenas, Gerardo Cedillo, Serguei Fomine, Manuel Salmon, Maria P Carreón-Castro
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Use of 4-piperidones in one-pot syntheses of novel, high-molecular-weight linear and virtually 100%-hyperbranched polymers

Alfredo R Cruz et al. Chem Commun (Camb). .

Abstract

4-Piperidone and 4-alkyl piperidones react selectively with aromatic hydrocarbons in a mixture of trifluoromethanesulfonic acid (TFSA) and CH(2)Cl(2) to give linear polymers, while N-(2-phenethyl)piperidone undergoes self-polymerization to yield virtually 100%-hyperbranched polymer.

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