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. 2009 Jul 29;131(29):9888-9.
doi: 10.1021/ja903679f.

Square tetrapalladium sheet sandwich complexes: cyclononatetraenyl as a versatile face-capping ligand

Tetsuro Murahashi  1 , Ryou Inoue, Kentaro Usui, Sensuke Ogoshi
Affiliations

Square tetrapalladium sheet sandwich complexes: cyclononatetraenyl as a versatile face-capping ligand

Tetsuro Murahashi et al. J Am Chem Soc. .

Abstract

An unusual square tetrapalladium sheet sandwich complex, [Pd(4)(mu(4)-C(9)H(9))(mu(4)-C(8)H(8))][B(Ar(f))(4)] has been isolated and structurally characterized. X-ray structure analysis showed that the square palladium sheet is flanked by the nine-membered cyclononatetraenyl and eight-membered cyclooctatetraene ligands to form a square metal sheet molecular sandwich structure. The coordinative unsaturation of the complex was revealed by phosphine titration experiments.

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