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. 2009 Sep 2;131(34):12028-9.
doi: 10.1021/ja903330j.

Stoichiometric control of multiple different tectons in coordination-driven self-assembly: preparation of fused metallacyclic polygons

Junseong Lee  1 , Koushik Ghosh, Peter J Stang
Affiliations

Stoichiometric control of multiple different tectons in coordination-driven self-assembly: preparation of fused metallacyclic polygons

Junseong Lee et al. J Am Chem Soc. .

Abstract

We present a general strategy for the synthesis of stable, multicomponent fused polygon complexes in which coordination-driven self-assembly allows for single supramolecular species to be formed from multicomponent self-assembly and the shape of the obtained polygons can be controlled simply by changing the ratio of individual components. The compounds have been characterized by multinuclear NMR spectroscopy and electrospray ionization mass spectrometry.

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Figures

Scheme 1
Scheme 1
Synthesis of Double Triangle 4.
Scheme 2
Scheme 2
Synthesis of Fused Rhomboid 7 & 8.
Figure 1
Figure 1
Calculated (top, blue) and experimental (bottom, red) ESI-MS spectrum (5+) and molecular force field model of double triangle 4 (A), double rhomboid 7 (B) and triple rhomboid 8 (C).
See this image and copyright information in PMC

References

    1. Li S-S, Yan H-J, Wan L-J, Yang H-B, Northrop BN, Stang PJ. J. Am. Chem. Soc. 2007;129:9268. - PubMed
    2. Seeman NC, Belcher AM. Proc. Natl. Acad. Sci. U.S.A. 2002;99:6451. - PMC - PubMed
    3. Balzani V, Credi A, Venturi M. Chem.-Eur. J. 2002;8:5524. - PubMed
    1. Stang PJ, Olenyuk B. Acc. Chem. Res. 1997;30:502.
    2. Leininger S, Olenyuk B, Stang PJ. Chem. Rev. 2000;100:853. - PubMed
    3. Seidel SR, Stang PJ. Acc. Chem. Res. 2002;35:972. - PubMed
    4. Schwab PFH, Levin MD, Michl J. Chem. Rev. 1999;99:1863. - PubMed
    5. Holliday BJ, Mirkin CA. Angew. Chem., Int. Ed. 2001;40:2022. - PubMed
    6. Cotton FA, Lin C, Murillo CA. Acc. Chem. Res. 2001;34:759. - PubMed
    7. Fujita M, Tominaga M, Hori A, Therrien B. Acc. Chem. Res. 2005;38:369. - PubMed
    8. Fiedler D, Leung DH, Bergman RG, Raymond KN. Acc. Chem. Res. 2005;38:349. - PubMed
    9. Ward MD. Chem. Commun. 2009:4487. - PubMed
    1. Stulz E, Ng Y-F, Scott SM, Sanders JKM. Chem. Commun. 2002:524. - PubMed
    2. Schmittel M, Mahata K. Angew. Chem. Int. Ed. Engl. 2008;47:5284. - PubMed
    3. Schmittel M, Kalsani V, Kishore RSK, Cölfen H, Bats JW. J. Am. Chem. Soc. 2005;127:11544. - PubMed
    4. Yang H-B, Ghosh K, Northrop BH, Zheng Y-R, Lyndon MM, Muddiman DC, Stang PJ. J. Am. Chem. Soc. 2007;129:14187. (c) - PMC - PubMed
    5. Ghosh K, Yang H-B, Northrop BH, Lyndon MM, Zheng Y-R, Muddiman DC, Stang PJ. J. Am. Chem. Soc. 2008;130:5320. - PubMed
    6. Baxter P, Lehn J-M, DeCian A, Fischer J. Angew. Chem. Int. Ed. Engl. 1993;32:69.
    7. Chichak KS, Cantrill SJ, Pease AR, Chiu S.-HCave, Atwood JL, Stoddart JF. Science. 2004;304:1308. G. W. V. - PubMed
    8. Cho YL, Uh HS, Chang S-Y, Chang H-Y, Choi M-G, Shin I, Jeong K-S. J. Am. Chem. Soc. 2001;123:1258. - PubMed
    1. Yang H,-B, Ghosh K, Northrop BH, Stang PJ. Org. Lett. 2007;9:1561. - PubMed
    2. Addicott C, Das N, Stang PJ. Inorg. Chem. 2004;43:5335. - PubMed
    3. Northrop BH, Yang H,-B, Stang PJ. Inorg. Chem. 2008;47:11257. - PMC - PubMed
    4. Zheng Y,-R, Yang H,-B, Northrop BH, Ghosh K, Stang PJ. Inorg. Chem. 2008;47:4706. - PubMed
    1. Yamanoi Y, Sakamoto Y, Kusukawa T, Fujita M, Sakamoto S, Yamaguchi K. J. Am. Chem. Soc. 2001;123:980. - PubMed

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