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. 2009 Oct 21;131(41):14654-5.
doi: 10.1021/ja907198n.

Pd(II)-catalyzed hydroxylation of arenes with 1 atm of O(2) or air

Yang-Hui Zhang  1 , Jin-Quan Yu
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Pd(II)-catalyzed hydroxylation of arenes with 1 atm of O(2) or air

Yang-Hui Zhang et al. J Am Chem Soc. .

Abstract

Pd(II)-catalyzed ortho-hydroxylation of variously substituted benzoic acids under 1 atm of O(2) or air is achieved under nonacidic conditions. Extensive labeling studies support a direct oxygenation of aryl C-H bonds with molecular oxygen.

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