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. 2009 Nov 28:(44):6810-2.
doi: 10.1039/b910501h. Epub 2009 Oct 5.

Multiple convergence in polyketide biosynthesis: a third folding mode to the anthraquinone chrysophanol

Gerhard Bringmann  1 , Tobias A M Gulder, Andreas Hamm, Michael Goodfellow, Hans-Peter Fiedler
Affiliations

Multiple convergence in polyketide biosynthesis: a third folding mode to the anthraquinone chrysophanol

Gerhard Bringmann et al. Chem Commun (Camb). .

Abstract

The polyketide chrysophanol is shown to be formed, in an organism-specific way, by a third folding mode, involving a remarkable cyclization of a bicyclic diketo precursor, thus establishing the first example of multiple convergence in polyketide biosynthesis.

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