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. 2010 Jan 4;16(1):276-81.
doi: 10.1002/chem.200902104.

An interpenetrated framework material with hysteretic CO(2) uptake

Karen L Mulfort  1 , Omar K Farha, Christos D Malliakas, Mercouri G Kanatzidis, Joseph T Hupp
Affiliations

An interpenetrated framework material with hysteretic CO(2) uptake

Karen L Mulfort et al. Chemistry. .

Abstract

A new, twofold interpenetrated metal-organic framework (MOF) material has been synthesized that demonstrates dramatic steps in the adsorption and hysteresis in the desorption of CO(2). Measurement of the structure by powder X-ray diffraction (PXRD) and pair distribution function (PDF) analysis indicates that structural changes upon CO(2) sorption most likely involve the interpenetrated frameworks moving with respect to each other.

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