doi: 10.1039/b918660c.
Epub 2009 Nov 26.
Rhodium-mediated activation of an alkane-type C-H bond
Affiliations
- PMID: 20024363
- DOI: 10.1039/b918660c
Item in Clipboard
Rhodium-mediated activation of an alkane-type C-H bond
Chem Commun (Camb).
.
Abstract
Abnormal C4-bonding of N-heterocyclic carbenes effectively modulates the electron density at rhodium and allows for the selective cleavage of an unactivated C(sp(3))-H bond, whereas no such intramolecular C-H bond breaking is observed when the carbene binds normally through the C2 carbon.
Similar articles
-
Microwave-promoted rhodium-catalyzed arylation of heterocycles through C--H bond activation.Angew Chem Int Ed Engl. 2006 Feb 27;45(10):1589-91. doi: 10.1002/anie.200504289. Angew Chem Int Ed Engl. 2006. PMID: 16444794 No abstract available.
-
Highly selective metal catalysts for intermolecular carbenoid insertion into primary C-H bonds and enantioselective C-C bond formation.Angew Chem Int Ed Engl. 2008;47(50):9747-51. doi: 10.1002/anie.200803157. Angew Chem Int Ed Engl. 2008. PMID: 18855950 No abstract available.
-
IPr* an easily accessible highly hindered N-heterocyclic carbene.Dalton Trans. 2010 Feb 14;39(6):1444-6. doi: 10.1039/b921894g. Epub 2009 Nov 27. Dalton Trans. 2010. PMID: 20104298
-
Guiding principles for site selective and stereoselective intermolecular C-H functionalization by donor/acceptor rhodium carbenes.Chem Soc Rev. 2011 Apr;40(4):1857-69. doi: 10.1039/c0cs00217h. Epub 2011 Mar 1. Chem Soc Rev. 2011. PMID: 21359404 Review.
-
N-Heterocyclic carbene complexes of rhodium: structure, stability and reactivity.Dalton Trans. 2008 Aug 21;(31):4079-94. doi: 10.1039/b802114g. Epub 2008 Jun 20. Dalton Trans. 2008. PMID: 18688424 Review.
Cited by
-
A Brief Survey of our Contribution to Stable Carbene Chemistry.Organometallics. 2011 Oct 24;30(20):5304-5313. doi: 10.1021/om200650x. Epub 2011 Sep 22. Organometallics. 2011. PMID: 22707843 Free PMC article.
Publication types
MeSH terms
Substances
LinkOut - more resources
Full Text Sources
Miscellaneous
