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. 2010;49(5):930-4.
doi: 10.1002/anie.200905801.

Carbonyl imines from oxaziridines: generation and cycloaddition of N-O=C dipoles

Katherine M Partridge  1 , Ilia A Guzei, Tehshik P Yoon
Affiliations

Carbonyl imines from oxaziridines: generation and cycloaddition of N-O=C dipoles

Katherine M Partridge et al. Angew Chem Int Ed Engl. 2010.
No abstract available

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Figures

Scheme 1
Scheme 1
Lewis acid-dependent formation of nitrones or carbonyl imines from N-sulfonyl oxaziridines. Ns = 4-nitrobenzenesulfonyl.
Scheme 2
Scheme 2
Cycloaddition of deuterium-labelled styrene.
Scheme 3
Scheme 3
Stereochemical probe in support of carbonyl imine intermediate 3.
Scheme 4
Scheme 4
Conversion of N-isoxazolidines to N-H-isoxazolidines or 1,3-aminoalcohols under complementary conditions.
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