This site needs JavaScript to work properly. Please enable it to take advantage of the complete set of features!

Skip to main page content

Add to Collections

Your saved search

Name of saved search:

Search terms:

Test search terms

Would you like email updates of new search results?

Yes
No

Email: (change)

Frequency:

Which day?

Which day?

Report format:

Send at most:

Send even when there aren't any new results

Optional text in email:

Your RSS Feed

. 2010 Feb 1;49(6):1123-7.

doi: 10.1002/anie.200904747.

Activation of allylic C-F bonds: palladium-catalyzed allylic amination of 3,3-difluoropropenes

Xavier Pigeon¹, Maxime Bergeron, Francis Barabé, Pascal Dubé, Heather N Frost, Jean-François Paquin

Affiliations

PMID: 20043303
DOI: 10.1002/anie.200904747

Activation of allylic C-F bonds: palladium-catalyzed allylic amination of 3,3-difluoropropenes

Xavier Pigeon et al. Angew Chem Int Ed Engl. 2010.

. 2010 Feb 1;49(6):1123-7.

doi: 10.1002/anie.200904747.

Authors

Xavier Pigeon¹, Maxime Bergeron, Francis Barabé, Pascal Dubé, Heather N Frost, Jean-François Paquin

Affiliation

¹ Département de chimie, Université Laval, 1045, avenue de la Médecine, Québec, QC, G1V 0A6, Canada.

PMID: 20043303
DOI: 10.1002/anie.200904747

No abstract available

PubMed Disclaimer

Similar articles

Palladium-catalyzed allylic C-H amination of alkenes with N-fluorodibenzenesulfonimide: water plays an important role.
Xiong T, Li Y, Mao L, Zhang Q, Zhang Q. Xiong T, et al. Chem Commun (Camb). 2012 Feb 21;48(16):2246-8. doi: 10.1039/c2cc16720d. Epub 2012 Jan 17. Chem Commun (Camb). 2012. PMID: 22252277
Pd-catalyzed olefination of perfluoroarenes with allyl esters.
Li Z, Zhang Y, Liu ZQ. Li Z, et al. Org Lett. 2012 Jan 6;14(1):74-7. doi: 10.1021/ol202859b. Epub 2011 Dec 8. Org Lett. 2012. PMID: 22148939
Palladium nanoparticle-catalyzed C-N bond formation. A highly regio- and stereoselective allylic amination by allyl acetates.
Adak L, Chattopadhyay K, Ranu BC. Adak L, et al. J Org Chem. 2009 May 15;74(10):3982-5. doi: 10.1021/jo9003037. J Org Chem. 2009. PMID: 19382763
Electrophilic activation of alkenes by platinum(II): so much more than a slow version of palladium(II).
Chianese AR, Lee SJ, Gagné MR. Chianese AR, et al. Angew Chem Int Ed Engl. 2007;46(22):4042-59. doi: 10.1002/anie.200603954. Angew Chem Int Ed Engl. 2007. PMID: 17487902 Review.
C-C, C-O, C-N bond formation on sp2 carbon by Pd(II)-catalyzed reactions involving oxidant agents.
Beccalli EM, Broggini G, Martinelli M, Sottocornola S. Beccalli EM, et al. Chem Rev. 2007 Nov;107(11):5318-65. doi: 10.1021/cr068006f. Epub 2007 Nov 1. Chem Rev. 2007. PMID: 17973536 Review. No abstract available.

See all similar articles

Cited by

Selective Quadruple C(sp³)-F Functionalization of Polyfluoroalkyl Ketones.
Xie T, Wang GQ, Wang YW, Rao W, Xu H, Li S, Shen ZL, Chu XQ. Xie T, et al. iScience. 2020 Jul 24;23(7):101259. doi: 10.1016/j.isci.2020.101259. Epub 2020 Jun 11. iScience. 2020. PMID: 32592997 Free PMC article.
Highly selective nickel-catalyzed gem-difluoropropargylation of unactivated alkylzinc reagents.
An L, Xu C, Zhang X. An L, et al. Nat Commun. 2017 Nov 13;8(1):1460. doi: 10.1038/s41467-017-01540-1. Nat Commun. 2017. PMID: 29133781 Free PMC article.
Desymmetrization of difluoromethylene groups by C-F bond activation.
Butcher TW, Yang JL, Amberg WM, Watkins NB, Wilkinson ND, Hartwig JF. Butcher TW, et al. Nature. 2020 Jul;583(7817):548-553. doi: 10.1038/s41586-020-2399-1. Epub 2020 Jun 1. Nature. 2020. PMID: 32480398 Free PMC article.
Structure-Based Design, Synthesis, and Biological Evaluation of Hsp90β-Selective Inhibitors.
Chaudhury S, Narasimharao Meka P, Banerjee M, Kent CN, Blagg BSJ. Chaudhury S, et al. Chemistry. 2021 Oct 21;27(59):14747-14764. doi: 10.1002/chem.202102574. Epub 2021 Sep 29. Chemistry. 2021. PMID: 34449940 Free PMC article.
Stereospecific Nickel-Catalyzed Cross-Electrophile Coupling Reaction of Alkyl Mesylates and Allylic Difluorides to Access Enantioenriched Vinyl Fluoride-Substituted Cyclopropanes.
Lin PC, Joshi C, McGinnis TM, Mallojjala SC, Sanford AB, Hirschi JS, Jarvo ER. Lin PC, et al. ACS Catal. 2023 Mar 20;13(7):4488-4499. doi: 10.1021/acscatal.3c00257. eCollection 2023 Apr 7. ACS Catal. 2023. PMID: 37066042 Free PMC article.

See all "Cited by" articles

Publication types

Actions

MeSH terms

Actions
Actions
Actions
Actions
Actions
Actions
Actions
Actions
Actions

Substances

Actions
Actions
Actions
Actions
Actions
Actions
Actions

LinkOut - more resources

Full Text Sources
- Wiley