Copper-catalysed bromoalkynylation of arynes
- PMID: 20062888
- DOI: 10.1039/b919301d
Copper-catalysed bromoalkynylation of arynes
Abstract
Arynes were found to be inserted into a C(sp)-Br sigma-bond of bromoalkynes in the presence of a copper catalyst, giving (alkynyl)bromoarenes in a straightforward manner.
Similar articles
-
Copper-catalysed three-component carboiodination of arynes: expeditious synthesis of o-alkynyl aryl iodides.Chem Commun (Camb). 2020 Jan 18;56(6):972-975. doi: 10.1039/c9cc09160b. Epub 2019 Dec 20. Chem Commun (Camb). 2020. PMID: 31859294
-
Copper-catalyzed 2:1 coupling reaction of arynes with alkynes.Org Lett. 2009 Jan 15;11(2):373-6. doi: 10.1021/ol802609j. Org Lett. 2009. PMID: 19072212
-
Straightforward construction of diarylmethane skeletons via aryne insertion into carbon-carbon sigma-bonds.Chem Commun (Camb). 2007 Apr 21;(15):1505-7. doi: 10.1039/b616768c. Epub 2007 Feb 5. Chem Commun (Camb). 2007. PMID: 17406688
-
Platinum-catalysed diborylation of arynes: synthesis and reaction of 1,2-diborylarenes.Chem Commun (Camb). 2010 Mar 14;46(10):1763-5. doi: 10.1039/b919407j. Epub 2010 Jan 13. Chem Commun (Camb). 2010. PMID: 20177642
-
Palladium-catalysed dimerisation-distannylation of arynes: synthesis and reaction of 2,2'-distannylbiaryls.Chem Commun (Camb). 2005 Dec 7;(45):5678-80. doi: 10.1039/b511773a. Epub 2005 Oct 18. Chem Commun (Camb). 2005. PMID: 16292388
Cited by
-
Total syntheses of chelidonine and norchelidonine via an enamide-benzyne-[2 + 2] cycloaddition cascade.Org Lett. 2012 Jun 1;14(11):2742-5. doi: 10.1021/ol300967a. Epub 2012 May 10. Org Lett. 2012. PMID: 22575071 Free PMC article.
-
Palladium-catalyzed annulation of arynes by o-halobenzamides: synthesis of phenanthridinones.J Org Chem. 2012 Oct 5;77(19):8648-56. doi: 10.1021/jo3016192. Epub 2012 Sep 26. J Org Chem. 2012. PMID: 23013049 Free PMC article.
-
CuI -Mediated Bromoalkynylation and Hydroalkynylation Reactions of Unsymmetrical Benzynes: Complementary Modes of Addition.Angew Chem Int Ed Engl. 2018 Dec 10;57(50):16564-16568. doi: 10.1002/anie.201811783. Epub 2018 Nov 15. Angew Chem Int Ed Engl. 2018. PMID: 30390400 Free PMC article.
-
Transition-metal-free alkynylation of aryl chlorides.Org Lett. 2011 Aug 19;13(16):4172-5. doi: 10.1021/ol2014736. Epub 2011 Jul 25. Org Lett. 2011. PMID: 21786825 Free PMC article.
-
Metal-Catalyzed Haloalkynylation Reactions.Chemistry. 2022 Jan 19;28(4):e202103046. doi: 10.1002/chem.202103046. Epub 2021 Nov 18. Chemistry. 2022. PMID: 34644433 Free PMC article. Review.
LinkOut - more resources
Full Text Sources