Enhanced electrokinetic (E/K) remediation on copper contaminated soil by CFW (carbonized foods waste)

Abstract

The E/K remediation method is presented to purify low permeable contaminated soils due to Cu(2+), and carbonized foods waste (CFW) was used as a permeable reactive barrier (PRB) material. For adsorption and precipitation of the Cu(2+) in the PRB during its motion, PRB was installed in a zone of rapidly changing pH values. The adsorption efficiency of CFW used as PRB material was found to be 4-8 times more efficient than that of Zeolite. Throughout the experiment, a voltage slope of 1V/cm was implemented and acetic acid was injected on the anode to increase the remediation efficiency. The electrode exchange was executed to more completely remove precipitated heavy metals in the vicinity of the cathode. The majority of Cu(2+) was adsorbed or sedimented by CFW prior to the exchange of the electrode, and the remaining quantity of precipitated Cu(2+) on the cathode had decreased with an increase in the operating time. Experiments of seven cases with different E/K operating times were performed, and the average removal ratios were 53.4-84.6%. The removal efficiencies for the majority of cases increased proportionally with an increase in the operating time. After the experiments were completed, the adsorbed Cu(2+) on CFW was 75-150 mg. This means that the role of CFW as the material in PRB for remediating heavy metals was confirmed. The cost of energies needed to remove Cu(2+), CFW, and acetic acid are estimated at US$ 13.3-40/m(3).