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. 2010 Feb 19;12(4):872-5.
doi: 10.1021/ol902929a.

Catalytic asymmetric total synthesis of tangutorine

Tetsuhiro Nemoto  1 , Eri Yamamoto, Robert Franzén, Takashi Fukuyama, Riliga Wu, Toshihiko Fukamachi, Hiroshi Kobayashi, Yasumasa Hamada
Affiliations

Catalytic asymmetric total synthesis of tangutorine

Tetsuhiro Nemoto et al. Org Lett. .

Abstract

The first enantioselective total synthesis of tangutorine has been achieved, wherein a Pd-catalyzed asymmetric allylic amination using a chiral diaminophosphine oxide (DIAPHOX) preligand was the key step.

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