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. 2010 Feb 22;16(8):2355-9.

doi: 10.1002/chem.200902313.

One-pot synthesis of unsymmetrical diaryl thioethers by palladium-catalyzed coupling of two aryl bromides and a thiol surrogate

Manuel A Fernández-Rodríguez¹, John F Hartwig

Affiliations

PMID: 20112309
PMCID: PMC3000801
DOI: 10.1002/chem.200902313

One-pot synthesis of unsymmetrical diaryl thioethers by palladium-catalyzed coupling of two aryl bromides and a thiol surrogate

Manuel A Fernández-Rodríguez et al. Chemistry. 2010.

. 2010 Feb 22;16(8):2355-9.

doi: 10.1002/chem.200902313.

Authors

Manuel A Fernández-Rodríguez¹, John F Hartwig

Affiliation

¹ Department of Chemistry, University of Illinois at Urbana-Champaign, 600 South Mathews Avenue, Urbana, IL 61801, USA.

PMID: 20112309
PMCID: PMC3000801
DOI: 10.1002/chem.200902313

No abstract available

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Figures

Scheme 1 — Scheme 1
Palladium-catalyzed synthesis of p-tolyl phenyl sulfide from phenyl triisopropylsilyl sulfide and p-bromotoluene.

Scheme 2 — Scheme 2
Tandem reaction between p-bromotoluene, TIPSSH, and chlorobenzene catalyzed by Pd(OAc)₂ and CyPF-tBu.

See this image and copyright information in PMC

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