doi: 10.1039/b919407j.
Epub 2010 Jan 13.
Platinum-catalysed diborylation of arynes: synthesis and reaction of 1,2-diborylarenes
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- PMID: 20177642
- DOI: 10.1039/b919407j
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Platinum-catalysed diborylation of arynes: synthesis and reaction of 1,2-diborylarenes
Chem Commun (Camb).
.
Abstract
Arynes are found to be facilely inserted into bis(pinacolato)diboron by using a platinum-isocyanide catalyst, affording diverse 1,2-diborylarenes, which can be converted into o-terphenyls via Suzuki-Miyaura coupling reaction.
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