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. 2010 Mar 14;46(10):1763-5.
doi: 10.1039/b919407j. Epub 2010 Jan 13.

Platinum-catalysed diborylation of arynes: synthesis and reaction of 1,2-diborylarenes

Hiroto Yoshida  1 , Kengo Okada, Shota Kawashima, Kenji Tanino, Joji Ohshita
Affiliations

Platinum-catalysed diborylation of arynes: synthesis and reaction of 1,2-diborylarenes

Hiroto Yoshida et al. Chem Commun (Camb). .

Abstract

Arynes are found to be facilely inserted into bis(pinacolato)diboron by using a platinum-isocyanide catalyst, affording diverse 1,2-diborylarenes, which can be converted into o-terphenyls via Suzuki-Miyaura coupling reaction.

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