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. 2010 Mar 24;132(11):3648-9.
doi: 10.1021/ja909522s.

Pd(II)-catalyzed ortho-trifluoromethylation of arenes using TFA as a promoter

Xisheng Wang  1 , Larry Truesdale, Jin-Quan Yu
Affiliations

Pd(II)-catalyzed ortho-trifluoromethylation of arenes using TFA as a promoter

Xisheng Wang et al. J Am Chem Soc. .

Abstract

A Pd(II)-catalyzed C-H activation/trifluoromethylation of arenes with an electrophilic trifluoromethylation reagent using diverse heterocycle directing groups is reported. The presence of trifluoroacetic acid is crucial for this catalytic reaction.

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