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. 2010 Apr 2;12(7):1448-51.
doi: 10.1021/ol100153h.

Gold(I)-catalyzed tandem cyclization approach to tetracyclic indolines

Yongxiang Liu  1 , Wenqing Xu, Xiang Wang
Affiliations

Gold(I)-catalyzed tandem cyclization approach to tetracyclic indolines

Yongxiang Liu et al. Org Lett. .

Abstract

Two highly stereoselective cationic gold(I)-catalyzed tandem cyclization reactions of alkynylindoles are described. These reactions demonstrated a novel and general strategy to rapidly construct highly functionalized polycyclic indolines. This approach was successfully employed for a formal synthesis of the akuammiline alkaloid minfiensine.

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