Nickel-catalyzed amination of aryl pivalates by the cleavage of aryl C-O bonds
- PMID: 20229558
- DOI: 10.1002/anie.200907287
Nickel-catalyzed amination of aryl pivalates by the cleavage of aryl C-O bonds
Abstract
Catalytic amination: The title reaction demonstrates the use of aryl carboxylates as suitable electrophilic coupling substrates in catalytic amination reactions. N-heterocyclic carbene ligands and NaOtBu promote the amination of aryl pivalates through the cleavage of normally unreactive aryl carbon-oxygen bonds (see scheme; cod=cyclooctadiene).
Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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