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. 2010 Apr 19;16(15):4442-6.
doi: 10.1002/chem.201000158. Epub 2010 Mar 15.

Influence of the N-bridging ligand on magnetic relaxation in an organometallic dysprosium single-molecule magnet

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Influence of the N-bridging ligand on magnetic relaxation in an organometallic dysprosium single-molecule magnet

Richard A Layfield et al. Chemistry. .

Abstract

Organometallic single-molecule magnet: Studies of two dimeric organometallic dysprosium compounds reveal one to be the first organometallic single-molecule magnet (see picture). A comparison of the magnetic properties and electronic structures of the two compounds shows that Dy⋅⋅⋅Dy interactions have a profound influence on the dynamic magnetic behaviour, while having little effect on the static magnetic measurements.

Keywords: density functional calculations; dysprosium; lanthanides; magnetic properties; organometallics; single-molecule magnetism.

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