Influence of the N-bridging ligand on magnetic relaxation in an organometallic dysprosium single-molecule magnet
- PMID: 20232441
- DOI: 10.1002/chem.201000158
Influence of the N-bridging ligand on magnetic relaxation in an organometallic dysprosium single-molecule magnet
Abstract
Organometallic single-molecule magnet: Studies of two dimeric organometallic dysprosium compounds reveal one to be the first organometallic single-molecule magnet (see picture). A comparison of the magnetic properties and electronic structures of the two compounds shows that Dy⋅⋅⋅Dy interactions have a profound influence on the dynamic magnetic behaviour, while having little effect on the static magnetic measurements.
Keywords: density functional calculations; dysprosium; lanthanides; magnetic properties; organometallics; single-molecule magnetism.
Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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