Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2010 Apr 7;46(13):2313-5.
doi: 10.1039/b923900f. Epub 2010 Jan 22.

Cationic Au(I) alkyne complexes: synthesis, structure and reactivity

Thomas N Hooper  1 , Michael Green, Christopher A Russell
Affiliations

Cationic Au(I) alkyne complexes: synthesis, structure and reactivity

Thomas N Hooper et al. Chem Commun (Camb). .

Abstract

Complexes of the type [(Bu(t)(3)P)Au(eta(2)-alkyne)][SbF(6)] can be accessed readily by treatment of CH(2)Cl(2) solutions of the alkyne with [AuCl(PBu(t)(3))]/AgSbF(6); when the alkyne carries one or two Me(3)Si substituents, desilylation reactions can occur leading to species with gold bonding in intricate bonding motifs to the C[triple bond]C fragments.

PubMed Disclaimer

LinkOut - more resources