Field-induced self-assembly of suspended colloidal membranes

Abstract

We report experiments that probe the self-assembly of micrometer-size colloids into one-particle-thick, robust, and self-healing membranes. In a magic-angle precessing magnetic field, superparamagnetic spheres experience isotropic pair attraction similar to the van der Waals force between atoms. But the many-body polarization interactions among them steer an ordered aggregation pathway consisting of growth of short chains, cross-linking and network formation, network coarsening, and consolidation of membrane patches. This generic aggregation scenario can be induced in any particles of large enough susceptibility.