Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2010 May 12;132(18):6282-3.
doi: 10.1021/ja100889h.

Metallosupramolecular tetragonal prisms via multicomponent coordination-driven template-free self-assembly

Ming Wang  1 , Yao-Rong Zheng, Koushik Ghosh, Peter J Stang
Affiliations

Metallosupramolecular tetragonal prisms via multicomponent coordination-driven template-free self-assembly

Ming Wang et al. J Am Chem Soc. .

Abstract

We present a general strategy for the synthesis of stable 3-D metallosupramolecular tetragonal prisms in which multicomponent coordination-driven self-assembly allows for single supramolecular species to be formed. The appropriate stoichiometric combination of a tetraphenylethylene-based tetratopic donor (1), a linear dipyridine donor (2), and a 90 degrees platinum metal complex (3) affords tetragonal prisms (4) as single products. The compounds have been characterized by multinuclear NMR spectroscopy and electrospray ionization mass spectrometry. The size of the supramolecules was determined by pulsed-gradient spin-echo NMR and modeled with molecular force field simulation methods.

PubMed Disclaimer

Figures

Figure 1
Figure 1
The 31P{1H} NMR spectra (121.4 MHz, 298K, CD2Cl2/CD3NO2 v : v = 2 : 1) of acceptor 3 (A) and tetragonal prism 4a (B)
Figure 2
Figure 2
Theoretical(blue) and experimental (red) ESI-MS spectra of tetragonal prism 4a
Figure 3
Figure 3
Molecular Modeling of tetragonal prism 4a
Scheme 1
Scheme 1
Multicomponent coordination-driven self-assembly of tetragonal prisms
See this image and copyright information in PMC

References

    1. Groll M, Dizel L, Lowe J, Stock D, Bochter M, Bartunik HD, Huber R. Nature. 1997;386:463. - PubMed
    1. Stang PJ, Olenyuk B. Acc. Chem. Res. 1997;30:502.
    2. Leininger S, Olenyuk B, Stang PJ. Chem. Rev. 2000;100:853. - PubMed
    3. Holliday BJ, Mirkin CA. Angew. Chem., Int. Ed. 2001;40:2022. - PubMed
    4. Seidel SR, Stang PJ. Acc. Chem. Res. 2002;35:972. - PubMed
    5. Fujita M, Tominaga M, Hori A, Terrien B. Acc. Chem. Res. 2005;38:369. - PubMed
    6. Oliver CG, Ulman PA, Wiester MJ, Mirkin CA. Acc. Chem. Res. 2008;41:1618. - PMC - PubMed
    7. Parkash MJ, Lah MS. Chem. Commun. 2009:3326. - PubMed
    1. Ghosh K, Yang H-B, Northrop BH, Lyndon MM, Zheng Y-R, Muddiman DC, Stang PJ. J. Am. Chem. Soc. 2008;130:5320. - PubMed
    2. Ghosh K, Hu J-M, White HS, Stang PJ. J. Am. Chem. Soc. 2009;131:6695. - PMC - PubMed
    3. Vacek J, Caskey DC, Horinek D, Shoemaker RK, Stang PJ, Michl J. J. Am. Chem. Soc. 2008;130:7629. - PubMed
    4. Pluth MD, Bergman RG, Raymond KN. J. Am. Chem. Soc. 2008;130:11423. - PubMed
    5. Mugridge JS, Bergman RG, Raymond KN. J. Am. Chem. Soc. 2010;132:1182. - PubMed
    1. Lehn JM, Eliseev AV. Science. 2001;291:2331. - PubMed
    2. Lehn JM. Chem. Eur. J. 1999;5:2455–2463.
    1. Northrop BH, Zheng Y-R, Chi K-W, Stang PJ. Acc. Chem. Res. 2009;42:1554. - PMC - PubMed
    2. Zheng Y-R, Yang H-B, Ghosh K, Zhao L, Stang PJ. Chem. Eur. J. 2009;15:7203. - PMC - PubMed
    3. Northrop BH, Yang H-B, Stang PJ. Inorg. Chem. 2008;47:11257. - PMC - PubMed
    4. Zheng Y-R, Yang H-B, Northrop BH, Ghosh K, Stang PJ. Inorg. Chem. 2008;47:4706. - PubMed
    5. Zheng Y-R, Northrop BH, Yang H-B, Zhao L, Stang PJ. J. Org. Chem. 2009;74:3554. - PMC - PubMed

Publication types