doi: 10.1039/b927028k.
Epub 2010 Apr 21.
Asymmetric hydrogenation of ketones catalyzed by a ruthenium(II)-indan-ambox complex
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- PMID: 20407691
- DOI: 10.1039/b927028k
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Asymmetric hydrogenation of ketones catalyzed by a ruthenium(II)-indan-ambox complex
Chem Commun (Camb).
.
Abstract
(S,R)-Indan-ambox ligand and its ruthenium(II) complex have been prepared and successfully applied to asymmetric hydrogenation of prochiral simple ketones. A wide range of unfunctionalized ketones are reduced by Ru(II)-indan-ambox catalyst with excellent enantioselectivities (up to 97% ee).
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