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. 2010 Jun 4;12(11):2450-2.
doi: 10.1021/ol1001686.

Efficient diacetoxylation of alkenes via Pd(II)/Pd(IV) process with peracetic acid and acetic anhydride

Chan Pil Park  1 , Joo Ho Lee, Kyung Soo Yoo, Kyung Woon Jung
Affiliations

Efficient diacetoxylation of alkenes via Pd(II)/Pd(IV) process with peracetic acid and acetic anhydride

Chan Pil Park et al. Org Lett. .

Abstract

A palladium-catalyzed diacetoxylation of alkenes in the presence of peracetic acid and acetic anhydride was developed to produce diacetates efficiently and diastereoselectively. Due to its mild conditions, this method was suitable for a broad range of substrates encompassing conjugated and nonconjugated olefins.

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Figures

Figure 1
Figure 1
Plausible Pd(II)/Pd(IV) pathway.
Scheme 1
Scheme 1
See this image and copyright information in PMC

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