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. 2010 Jun 30;132(25):8536-7.
doi: 10.1021/ja102753d.

Catalytic asymmetric transacetalization

Ilija Corić  1 , Sreekumar Vellalath, Benjamin List
Affiliations

Catalytic asymmetric transacetalization

Ilija Corić et al. J Am Chem Soc. .

Erratum in

  • J Am Chem Soc. 2010 Sep 1;132(34):12155

Abstract

A catalytic enantioselective transacetalization has been developed. The chiral phosphoric acid TRIP was demonstrated to be an efficient and highly enantioselective catalyst for the activation of O,O-acetals. The reaction enables the asymmetric synthesis of acetals with the acetal carbon as the only stereogenic center.

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