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. 2010 Jul 2;12(13):3054-7.
doi: 10.1021/ol101069y.

Development of chiral terminal-alkene-phosphine hybrid ligands for palladium-catalyzed asymmetric allylic substitutions

Zhaoqun Liu  1 , Haifeng Du
Affiliations

Development of chiral terminal-alkene-phosphine hybrid ligands for palladium-catalyzed asymmetric allylic substitutions

Zhaoqun Liu et al. Org Lett. .

Abstract

A variety of novel chiral terminal-alkene-phosphine hybrid ligands were successfully developed from diethyl L-tartrate for palladium-catalyzed asymmetric allylic alkylations, etherifications, and amination to give the desired products in excellent yields and ee's.

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