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. 2010 Aug 7;46(29):5322-4.
doi: 10.1039/c0cc00525h. Epub 2010 Jun 24.

Rational design of efficient rhodium catalysts for the anti-Markovnikov oxidative amination of styrene

M Victoria Jiménez  1 , Jesús J Pérez-Torrente, M Isabel Bartolomé, Fernando J Lahoz, Luis A Oro
Affiliations

Rational design of efficient rhodium catalysts for the anti-Markovnikov oxidative amination of styrene

M Victoria Jiménez et al. Chem Commun (Camb). .

Abstract

Cationic rhodium(I) complexes containing the flexible hemilabile phosphine ligand (3-ethoxypropyl)diphenylphosphine efficiently catalyzed the anti-Markovnikov oxidative amination of styrene in tetrahydrofurane at 80 degrees C to produce (E)-1-styrylpiperidine with turnover frequencies up to 75 h(-1) with excellent enamine selectivity (96%).

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